网上有关“卤族元素性质递变规律是什么?”话题很是火热,小编也是针对卤族元素性质递变规律是什么?寻找了一些与之相关的一些信息进行分析,如果能碰巧解决你现在面临的问题,希望能够帮助到您。
卤素F→Cl →Br →I。
随着原子序数的递增,原子半径逐渐增大,原子核对最外层电子的引力逐渐减小,卤素原子得电子的能力逐渐减弱,非金属性逐渐减弱。元素的非金属性强弱可以从其最高价氧化物的水化物的酸性强弱,或与氢气生成气态氢化物的难易程度以及氢化物的稳定性来判断。
扩展资料:
注意事项:
熔点:氟化氢大于碘化氢大于溴化氢大于氯化氢,原因是氟化氢有氢键,所以熔点最高,其他随分子量变大分子间作用力增大,熔点逐渐升高。
但是HF由于F的电负性很强,导致HF分子之间还存在一种特殊的分子间作用力——氢键,而氢键的强度介于化学键、范德华力之间,造成HF的分子间作用力最强。
百度百科-卤族元素
下列对一些实验事实的理论解释正确的是() 选项 实验事实 理论解释 A MgCl2溶液中加入
氟化氢(化学式:HF)是一种极强的腐蚀剂,有剧毒。它是无色的气体,但是在[空气]]中,只要超过3ppm就会产生刺激的味道。
由於氟原子电负性很大,所以会与氢原子形成氢键的缘故,所以沸点较氯化氢、溴化氢、碘化氢等为高。
其水溶液氢氟酸是一种弱酸,但氢氟酸本身具对矽(硅)及二氧化硅有极强的侵蚀能力。 故可腐蚀玻璃(主要成分是二氧化硅及硅酸盐),是唯一可腐蚀玻璃的酸,所以日常贮存要使用塑料瓶或铅制容器。
氢氟酸可以腹?し麴つぁ⒑粑?兰俺ξ傅牢?眨?舨簧鞣⑸?夥?岜┞叮?α⒓从么罅壳逅?逑?0至30分钟,然后以葡萄酸钙软膏或药水涂抹;若不小心误饮,则要立即喝下大量的高钙牛奶,然后紧急送医处理。
帮助编辑氟化氢
[[Image:]]
常规
别名
IUPAC中文命名 氟化氢
CAS号 [7664-39-3 [7664-39-3]]
分子式 HF
摩尔质量 20.0063 g/mol
SMILES
InChI
溶解度
pKa 3.15
pI
物理性质
熔点 ?83.38 C (189.77 K)
沸点 19.54°C (293.15 K)
三相点
临界点
偶极矩
熔化热(Δfus H) kJ/mol
汽化热(Δvap H) kJ/mol
[α]D20 °mL/g/dm ()
相态名称
外观 无色气体
密度 0.818 g/L kg/m3
Δf HmO kJ/mol
Δf GmO kJ/mol
SmO J/mol/K
Δc HmO kJ/mol
Cm J/mol/K
黏度
安全性
主要危险 剧毒, 腐蚀性
闪点 ?37.8°C
Hydrofluoric acid is a highly toxic and corrosive solution of hydrogen fluoride in water. Neat hydrogen fluoride is sometimes called anhydrous hydrofluoric acid. Hydrofluoric acid is notoriously known to dissolve glass by reacting with SiO2, the major component of most glasses:
SiO2(s) + 4HF(aq) → SiF4(g) + 2H2O(l)
or
SiO2(s) + 6HF(aq) → H2[SiF6](aq) + 2H2O(l)
Consequently, it must be stored in polyethylene or Teflon containers. It is also unique in its ability to dissolve almost all inorganic metal and semimetal oxides. Because of its low tendency to dissociate into H+ and F- ions in water, it is properly considered a weak acid, but it is nonetheless extremely corrosive and poisonous, as explained below.
Production
Industrially, hydrofluoric acid is produced from the mineral fluorite, also known as calcium fluoride (CaF2) and concentrated sulfuric acid. When combined at 250°C, these two substances react to produce hydrogen fluoride according to the following chemical equation:
CaF2 + H2SO4 → 2HF + CaSO4
The vapors from this reaction are a mixture of hydrogen fluoride, sulfuric acid, and a few minor byproducts, from which hydrogen fluoride can be isolated by distillation.
Hydrofluoric acid is a known hazard in car engine fires, forming when Viton o-rings and hoses are exposed to temperatures in excess of 400°C.
Uses
Hydrofluoric acid's ability to dissolve oxides makes it important in the purification of both aluminium and uranium. It is also used to etch glass, to remove surface oxides from silicon in the semiconductor industry, as a catalyst for the alkilation of iso-butane and butene in oil refineries and to remove oxide impurities from stainless steel in a process called pickling. Recently it has even been used in car washes in "wheel cleaner" compounds.[1] Due to its ability to dissolve silicate compounds, hydrofluoric acid is often used during the rock and mineral analysis process to dissolve rock samples (usually powdered) prior to analysis.
Hydrofluoric acid is also used in the synthesis of many fluorine-containing organic compounds, including teflon and refrigerants such as freon.
A.MgCl2溶液中加入浓氨水,出现白色沉淀,是因Qc>Ksp,不能比较碱性的强弱,故A错误;
B.用pH试纸测得CH3COONH4溶液的pH=7,则醋酸根离子与铵根离子水解程度相同,故B错误;
C.氟化氢的沸点高于氯化氢,是因HF分子间存在氢键,而HCl分子间几乎不存在氢键,故C正确;
D.将SO2气体通入氯水中,氯水褪色,是因SO2具有还原性,故D错误;
故选C.
关于“卤族元素性质递变规律是什么?”这个话题的介绍,今天小编就给大家分享完了,如果对你有所帮助请保持对本站的关注!
本文来自作者[烟花巷陌]投稿,不代表盛龙号立场,如若转载,请注明出处:https://snlon.net/sn/44701.html
评论列表(3条)
我是盛龙号的签约作者“烟花巷陌”
本文概览:网上有关“卤族元素性质递变规律是什么?”话题很是火热,小编也是针对卤族元素性质递变规律是什么?寻找了一些与之相关的一些信息进行分析,如果能碰巧解决你现在面临的问题,希望能够帮助...
文章不错《卤族元素性质递变规律是什么?_1》内容很有帮助